silyl hydride

silyl hydride
силгидрид

English-Russian dictionary of chemistre. 2014.

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  • Brook rearrangement — The Brook rearrangement in organic chemistry is a rearrangement reaction in which a organosilyl group switches position with a hydroxyl proton over a carbon to oxygen covalent bond under the influence of a base [cite journal | author = A. G.… …   Wikipedia

  • Organosilicon — compounds are organic compounds containing carbon silicon bonds. Organosilicon chemistry is the corresponding science exploring their properties and reactivity.[1] Like carbon, the organically bound silicon is tetravalent and tetrahedral. Carbon… …   Wikipedia

  • Danishefsky Taxol total synthesis — overview from raw material perspective The Danishefsky Taxol total synthesis in organic chemistry is an important third Taxol synthesis published by the group of Samuel Danishefsky in 1996 [1] two years after the first two efforts …   Wikipedia

  • Protecting group — A protecting group or protective group is introduced into a molecule by chemical modification of a functional group in order to obtain chemoselectivity in a subsequent chemical reaction. It plays an important role in multistep organic synthesis.… …   Wikipedia

  • Silanes — This article is about a class of chemical compounds. For the compound with chemical formula SiH4, see Silane. Silanes are chemical compounds of silicon and hydrogen, which are analogues of alkane hydrocarbons. Silanes consist of a chain of… …   Wikipedia

  • Intramolecular — in chemistry describes a process or characteristic limited within the structure of a single molecule; a property or phenomenon limited to the extent of a single molecule. Examples * intramolecular hydride transfer (transfer of a hydride ion from… …   Wikipedia

  • Intramolecular reaction — Intramolecular in chemistry describes a process or characteristic limited within the structure of a single molecule, a property or phenomenon limited to the extent of a single molecule. Contents 1 Examples 2 Molecular tethers 3 See also …   Wikipedia

  • Mukaiyama Taxol total synthesis — overview from raw material perspective The Mukaiyama taxol total synthesis published by the group of Teruaki Mukaiyama of the Tokyo University of Science between 1997 and 1999 was the 6th successful taxol total synthesis. The total synthesis of… …   Wikipedia

  • Peterson olefination — The Peterson olefination (also called the Peterson reaction) is the chemical reaction of α silyl carbanions 1 with ketones (or aldehydes) to form a β hydroxysilane 2 which eliminates to form alkenes 3.cite journal | author = D. J. Peterson |… …   Wikipedia

  • Desulfonylation reactions — are chemical reactions leading to the removal of a sulfonyl group from organic compounds. As the sulfonyl functional group is electron withdrawing, methods for cleaving the sulfur carbon bonds of sulfones are typically reductive in nature.… …   Wikipedia

  • Wender Taxol total synthesis — starting from a naturally occurring compound with ring construction in the order A,B,C,D. The Wender effort is shorter by approximately 10 steps. Raw materials for the preparation of Taxol by this route include verbenone, prenyl bromine, allyl… …   Wikipedia


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